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1 article(s) from Schreyer, Matthias

Is the tungsten(IV) complex (NEt₄)₂[WO(mnt)₂] a functional analogue of acetylene hydratase?

Matthias Schreyer and
Lukas Hintermann

Beilstein J. Org. Chem. 2017, 13, 2332–2339, doi:10.3762/bjoc.13.230

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Scheme 1: a) Acetylene hydratase catalyzes the hydration of acetylene to ethanal. b) Currently favored key-st...

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Scheme 2: a) π-Activation pathway in Markovnikov selective alkyne hydration, e.g., with mercury catalysts. b)...

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Scheme 3: a) Synthesis of complex (NEt₄)₂[WO(mnt)₂] (1) [29]. b) Attempted catalytic hydration reaction with a te...

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Scheme 4: a) Unexpected isolation of acetone 2,4-dinitrophenylhydrazone (10) from an attempted catalytic hydr...

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Figure 1: Frequency of reported melting points for acetaldehyde 2,4-dinitrophenylhydrazone (9) from the Reaxy...

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Figure 2: Experimental setup for the study of catalytic acetylene hydration. Red arrows indicate the directio...

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Figure 3: Identification of ethyne (2) in the reaction solution by coupling pattern analysis of ¹³C-satellite...

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Published 02 Nov 2017

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Is the tungsten(IV) complex (NEt4)2[WO(mnt)2] a functional analogue of acetylene hydratase?

Is the tungsten(IV) complex (NEt₄)₂[WO(mnt)₂] a functional analogue of acetylene hydratase?